Modelling and optimization of modular system for power generation from a salinity gradient

© 2019 Elsevier Ltd Pressure retarded osmosis has been proposed for power generation from a salinity gradient resource. The process has been promoted as a promising technology for power generation from renewable resources, but most of the experimental work has been done on a laboratory size units. To date, pressure retarded osmosis optimization and operation is based on parametric studies performed on laboratory scale units, which leaves a gap in our understanding of the process behaviour in a full-scale modular system. A computer model has been developed to predict the process performance. Process modelling was performed on a full-scale membrane module and impact of key operating parameters such as hydraulic feed pressure and feed and draw solution rates were evaluated. Results showed that the optimum fraction of feed/draw solution in a mixture is less than what has been earlier proposed ratio of 50% and it is entirely dependent on the salinity gradient resource concentration. Furthermore, the optimized pressure retarded osmosis process requires a hydraulic pressure less than that in the normal (unoptimized) process. The results here demonstrate that the energy output from the optimized pressure regarded osmosis process is up to 54% higher than that in the normal (unoptimized) process

Novel Thermal Desalination Brine Reject-Sewage Effluent Salinity Gradient for Power Generation and Dilution of Brine Reject

Salinity gradient resource presents an essential role for power generated in the process of pressure-retarded osmosis (PRO). Researchers proposed several designs for coupling the PRO process with the desalination plants, particularly reverse osmosis technology for low-cost desalination but there is no study available yet on the utilization of the concentrated brine reject from a thermal desalination plant. This study evaluates the feasibility of power generation in the PRO process using thermal plant brine reject-tertiary sewage effluent (TSE) salinity gradient resource. Power generation in the PRO process was determined for several commercially available FO membranes. Water flux in Oasys Forward Osmosis membrane was more than 31 L/m2h while the average water flux in the Oasys module was 17 L/m2h. The specific power generation was higher in the thin film composite (TFC) membranes compared to the cellulose triacetate (CTA) membranes. The specific power generation for the Oasys membrane was 0.194 kWh/m3, which is 41% of the maximum Gibbs energy of the brine reject-TSE salinity gradient. However, the Hydration Technology Innovation CTA membrane extracted only 0.133 kWh/m3 or 28% of Gibbs free energy of mixing for brine reject-TSE salinity gradient. The study reveals the potential of the brine reject-TSE salinity gradient resource for power generation and the dilution of brine reject

Enhanced Performance Dual Stage Pressure Retarded Osmosis

© 2017 The Authors. Published by Elsevier Ltd. A dual stage PRO process has been proposed for power generation from a salinity gradient across a semi-permeable membrane. Both closed-loop and open-loop dual stage PRO system were evaluated using 2 M NaCl and Dead Sea as draw solutions, whereas the feed solution was either fresh water or seawater. The impact of feed salinity gradient resource and feed pressure on the net power generation and water flux were evaluated. DSPRO can be combined with desalination plant using seawater brine as the draw solution either in closed-loop or open-loop. This hybridization has multiple applications such as reducing the impact of discharging concentrated brine to sea, energy storage, and increase the recovery rate of the desalination. Power generation by DSPRO will reduce the energy consumption by the desalination processes. Waste heat from power plants can be used for the regeneration of the draw solution in the closed-loop DSPRO. Process modelling has been performed and shown promising results for DSPRO application for power generation

Process simulation of ion exchange desalination treatment of coal seam gas associated water

© 2018 Elsevier Ltd The aim of this investigation was to develop an ion exchange process for the remediation of coal seam gas (CSG) associated water to make it suitable for beneficial reuse. The hypothesis was that computational modelling could accelerate the selection of appropriate ion exchange desalination strategies. Hence, we applied AqMB water process engineering software to predict which combination of weak acid cation (WAC), strong acid cation (SAC), weak base anion (WBA) and strong base anion (SBA) resins were most appropriate. Simulation results revealed that both SAC/WBA and SAC/SBA resin combinations were unable to meet water beneficial reuse standards for conductivity (< 950 μS/cm) due to the presence of bicarbonate species (4973 and 1918 μS/cm, respectively). Thus, a degasser unit was necessary to remove the large concentrations (ca. 1328 mg/L) of dissolved carbon dioxide formed due to decomposition of bicarbonate/carbonate species under acidic conditions in the cation resin stages. pH adjustment of effluent from the preferred SBA resin with acid not only did not meet solution conductivity guidelines but also raised the concentration of chloride or sulphate ions to levels, which may be detrimental for crop growth. Addition of a WAC resin allowed production of high quality water (either SAC/SBA/WAC or WAC/SAC/SBA combinations). To comply with sodium adsorption ratio requirements for irrigating soil it was suggested to apply micronized gypsum to the treated water. Economic evaluation suggested the treated water cost was A$1003 (WAC/SAC/SBA) to A$1276 (SAC/SBA/WAC) per ML treated which was comparable to estimated costs for a reverse osmosis desalination system

Integration and optimization of pressure retarded osmosis with reverse osmosis for power generation and high efficiency desalination

© 2016 Elsevier Ltd. Salinity gradient power is proposed as a source of renewable energy when two solutions of different salinity are mixed. In particular, Pressure Retarded Osmosis (PRO) coupled with a Reverse Osmosis process (RO) has been previously suggested for power generation, using RO brine as the draw solution. However, integration of PRO with RO may have further value for increasing the extent of water recovery in a desalination process. Consequently, this study was designed to model the impact of various system parameters to better understand how to design and operate practical PRO-RO units. The impact of feed salinity and recovery rate for the RO process on the concentration of draw solution, feed pressure, and membrane area of the PRO process was evaluated. The PRO system was designed to operate at maximum power density of δP=δπ2. Model results showed that the PRO power density generated intensified with increasing seawater salinity and RO recovery rate. For an RO process operating at 52% recovery rate and 35 g/L feed salinity, a maximum power density of 24 W/m2 was achieved using 4.5 M NaCl draw solution. When seawater salinity increased to 45 g/L and the RO recovery rate was 46%, the PRO power density increased to 28 W/m2 using 5 M NaCl draw solution. The PRO system was able to increase the recovery rate of the RO by up to 18% depending on seawater salinity and RO recovery rate. This result suggested a potential advantage of coupling PRO process with RO system to increase the recovery rate of the desalination process and reduce brine discharge

The application of pressure-driven ceramic membrane technology for the treatment of industrial wastewaters – A review

© 2018 Elsevier B.V. This paper presents a review of the previous laboratory analysis and case studies on the application of the pressure-driven ceramic membrane technology for treatment of industrial wastewaters. Ceramic membranes has attracted remarkable interests in recent decades for industrial wastewater treatment because of their superior characteristic such as high fluxes, reliable working lifetime under aggressive operating conditions and ease of cleaning. The literature review revealed that the efficiency of this technology has been proven in a wide variety of wastewaters from different industries and activities including pulp and paper, textile, pharmaceutical, petrochemical, food and mining. However, there are still challenges and questions for this technology that need to be addressed in future researches such as investment cost optimisation by introducing new fabrication technologies, selectivity, permeability and packing densities improvement, fouling minimisation and proposing scale up based on experimental research results

Energy efficiency of hollow fibre membrane module in the forward osmosis seawater desalination process

© 2019 This study provided new insights regarding the energy efficiency of hollow fibre forward osmosis modules for seawater desalination; and as a consequence an approach was developed to improve the process performance. Previous analysis overlooked the relationship between the energy efficiency and operating modes of the hollow fibre forward osmosis membrane when the process was scaled-up. In this study, the module length and operating parameters were incorporated in the design of an energy-efficient forward osmosis system. The minimum specific power consumption for seawater desalination was calculated at the thermodynamic limits. Two FO operating modes: (1) draw solution in the lumen and (2) feed solution in the lumen, were evaluated in terms of the desalination energy requirements at a minimum draw solution flow rate. The results revealed that the operating mode of the forward osmosis membrane was important in terms of reducing the desalination energy. In addition, the length of the forward osmosis module was also a significant factor and surprisingly increasing the length of the forward osmosis module was not always advantageous in improving the performance. The study outcomes also showed that seawater desalination by the forward osmosis process was less energy efficient at low and high osmotic draw solution concentration and performed better at 1.2–1.4 M sodium chloride draw solution concentrations. The findings of this study provided a platform to the manufacturers and operators of hollow fibre forward osmosis membrane to improve the energy efficiency of the desalination process

Progress in osmotic membrane bioreactors research: Contaminant removal, microbial community and bioenergy production in wastewater.

Renewable energy, water conservation, and environmental protection are the most important challenges today. Osmotic membrane bioreactor (OMBR) is an innovative process showing superior performance in bioenergy production, eliminating contaminants, and low fouling tendency. However, salinity build-up is the main drawback of this process. Identifying the microbial community can improve the process in bioenergy production and contaminant treatment. This review aims to study the recent progress and challenges of OMBRs in contaminant removal, microbial communities and bioenergy production. OMBRs are widely reported to remove over 80% of total organic carbon, PO43-, NH4+ and emerging contaminants from wastewater. The most important microbial phyla for both hydrogen and methane production in OMBR are Firmicutes, Proteobacteria and Bacteroidetes. Firmicutes' dominance in anaerobic processes is considerably increased from usually 20% at the beginning to 80% under stable condition. Overall, OMBR process has great potential to be applied for simultaneous bioenergy production and wastewater treatment

π-Projective Semimodule Over Semiring

سابقا تم دراسة&nbsp; مفهوم المقاس الاسقاطي من النوع π على&nbsp; الحلقة من قبل عدة مؤلفين. في هذا البحث هذا المفهوم سيقدم ويعمم لشبه المقاس على شبه الحلقة. ليكنT شبه مقاس يساري وحدوي, فنقول انه اسقاطي من النوع π اذا كان لكل شبه مقاسين جزئيين منه بشرط ان شبه المقاس يساوي مجموع هذين الشبه المقاسين الجزئيين,&nbsp; فيوجد تشاكلين بحيث ان التشاكل الاول مجموعة جزئية من احد شبه المقاسين الجزئيين,&nbsp; والتشاكل الثاني مجموعة جزئية من الاخر و مجموع التشاكلين يساوي الدالة الاحادية بالنسبة لشبه المقاس المعطى.&nbsp;&nbsp; Previously the concept of π-projective modules over ring was studied by some authors. The aim of this research is to give a comprehensive study of π-projective semimodule and access to some new properties and characterizations for this class of semimodules.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Let S be a commutative semiring with identity 1≠0 and T a unital left semimodule, then we say that T is π-projective &nbsp;if for every two subsemimodules M and L of T with T=M+L, there exist f and g ϵEnd(T), such that f +g=1T,&nbsp; f(T) M and g(T) L

Single and dual stage closed-loop pressure retarded osmosis for power generation: Feasibility and performance

© 2017 Elsevier Ltd This work proposes an analysis of conventional (single stage) and dual stage Closed-Loop Pressure Retarded Osmosis (CLPRO) for power generation from a salinity gradient resource. Model calculations were performed taking into account the influence of operating parameters such as the draw solution concentration, membrane area, and draw solution pressure on the performance of the CLPRO process. Modeling results showed that the dual stage CLPRO process outperformed the conventional CLPRO process and power generation increased 18% by adding a second stage of PRO membrane. Multi-Effect Distillation (MED) was selected for the regeneration of the draw solution taking advantage of an available source of waste heat energy. The performance of MED process has been assessed by investigating two key parameters: the specific thermal consumption and the specific heat transfer area. The model calculations showed that the power generation by the single and dual stage CLPRO was higher than the electrical power consumption by the MED plant. In the case of the power generation obtained by the dual stage CLPRO, it was 95% higher than the electrical power consumption by the MED plant, proving the possibility of using low-grade heat for producing electricity from a salinity gradient resource